Tc, Pc (Van der Waals)

Tc = 8a/(27Rb); Pc = a/(27b²).
Created by
Renato Passos, Eng. de Software
Reviewed by
Renato Passos, Eng. de Software

Last updated: Apr 18, 2026

Tc (K)
303,4

About this calculator

The Van der Waals Critical Point Calculator is an online tool that calculates the critical temperature (Tc) and critical pressure (Pc) of a real gas. The Van der Waals equation is a correction to the ideal gas law, considering the interactions between molecules and the volume occupied by them. The formula for Tc is 8a/(27Rb) and for Pc is a/(27b²), where a and b are gas-specific constants.

The Van der Waals equation is fundamental to understanding the behavior of real gases, especially near the critical point. The critical point is a state where the properties of liquid and vapor become identical, characterized by Tc and Pc. The calculator uses these formulas to provide accurate values for these parameters.

These calculations are essential in various fields, such as chemical engineering, physics, and industrial chemistry. They allow predicting the behavior of substances under different conditions, which is crucial for the design and operation of chemical and industrial processes.

When using the calculator, it is essential to remember that the constants a and b vary for each gas and must be precisely known to obtain correct results. Additionally, the Van der Waals equation is an approximation and may not be valid for all gases or conditions.

Frequently asked questions

What are the constants a and b in the Van der Waals equation?

The constants a and b are gas-specific parameters that account for the interactions between molecules and the volume occupied by them.

How do I obtain the values of a and b for a specific gas?

The values of a and b can be found in gas properties tables or obtained experimentally.

Is the Van der Waals equation valid for all gases?

No, the Van der Waals equation is an approximation and may not be valid for all gases or conditions, especially at high pressures or low temperatures.

Can I use the calculator for gases not in the periodic table?

The calculator can be used for any gas, provided you know the specific constants a and b for that gas.

What are the units of the constants a and b?

The units of a are Pa·m⁶/mol² and of b are m³/mol.

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