Meia-vida ordem 1

t½ = 0,693/k.
Created by
Renato Passos, Eng. de Software
Reviewed by
Renato Passos, Eng. de Software

Last updated: Apr 18, 2026

69,30 s

About this calculator

The half-life calculator for first-order reactions is a tool to determine the time required for a reactant's concentration to reduce to half. It uses the formula t½ = 0.693/k, where k is the rate constant. This calculation is crucial in chemistry, especially in chemical kinetics, to predict decay or decomposition times in processes like radioactive disintegration or controlled chemical reactions.

To use the calculator, input the rate constant (k) in the correct unit. The half-life is directly proportional to the natural logarithm of 2 (0.693) and inversely proportional to k. This means reactions with higher k values (faster rates) have shorter half-lives. The result is applied in fields like pharmacology, radiology, and chemical engineering to model exponential decay processes.

This tool is intended for first-order reactions, where the rate depends linearly on the concentration of a single reactant. Ensure the k values are accurate and in compatible units (s⁻¹, min⁻¹, etc.). Avoid using it for zero or second-order reactions, as the first-order formula does not apply to other kinetic orders.

Common precautions include verifying the reaction's order and the precision of units. Frequent errors occur when mixing half-lives of different orders or inputting k values without confirming the reaction type. Always consult an expert if unsure about the model's applicability in real scenarios, such as radioactive isotope analysis or drug kinetics.

Frequently asked questions

What's the difference between first-order and zero-order half-life?

In first-order, half-life is constant and independent of initial concentration, while in zero-order it varies proportionally with initial concentration.

Why is the value 0.693 used in the formula?

This is the natural logarithm of 2 (ln(2)), derived from integrating the differential equation of a first-order reaction.

Can I use this calculator for second-order reactions?

No, the t½ = 0.693/k formula is specific to first-order reactions. Second-order reactions use a different formula.

How to ensure the rate constant unit is correct?

The rate constant (k) should be in units of time⁻¹ (e.g., s⁻¹). Verify the reaction order and experimental context to confirm.

Is this calculator useful in pharmacology?

Yes, it helps predict drug elimination time in the body based on first-order kinetics.

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