ΔS Vaporização (Trouton)

~88 J/(mol·K).
Created by
Renato Passos, Eng. de Software
Reviewed by
Renato Passos, Eng. de Software

Last updated: Apr 18, 2026

J/(mol·K)
88

About this calculator

The vaporization entropy calculator, known as Trouton, is a tool that estimates the entropy change (ΔS) during the vaporization process of a substance. Entropy is a measure of the disorder or randomness of a system, and during vaporization, molecules gain energy and become more dispersed, increasing the system's entropy. The formula used is based on Trouton's rule, which states that the vaporization entropy is approximately equal to 88 J/(mol·K) for many substances.

The formula behind the calculator is ΔS = ΔH / T, where ΔH is the enthalpy of vaporization and T is the boiling point in Kelvin. However, Trouton's rule provides a simpler approximation, considering ΔS to be approximately constant and equal to 88 J/(mol·K). This is useful when precise data on enthalpy and temperature are not available.

The vaporization entropy calculator is particularly useful in chemical and physical processes involving phase changes, such as distillation, evaporation, or condensation. It helps to understand and predict the behavior of substances during these changes, being essential for the design and optimization of industrial processes.

It is important to be aware of the limitations of Trouton's rule, as it does not apply to all substances and conditions. For more accurate results, especially in complex systems or under non-standard conditions, it is recommended to use experimental data or more advanced models.

Frequently asked questions

What is Trouton's rule?

Trouton's rule is an approximation that states the vaporization entropy of a substance is approximately equal to 88 J/(mol·K).

When to use the vaporization entropy calculator?

Use it when you need to estimate the entropy change during the vaporization of a substance, especially in chemical and physical processes involving phase changes.

Is Trouton's rule accurate for all substances?

No, Trouton's rule has limitations and does not apply to all substances and conditions. For more accurate results, use experimental data or more advanced models.

What are the units of vaporization entropy?

The units of vaporization entropy are J/(mol·K).

Can I use the calculator for substances not listed?

Yes, the calculator can be used for any substance, but keep in mind that accuracy may vary depending on the substance and specific conditions.

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